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Beilstein J. Org. Chem. 2014, 10, 746–751, doi:10.3762/bjoc.10.69
Graphical Abstract
Scheme 1: Previous work for (R)-(1-amino-3-methylbutyl)boronic acid synthesis.
Scheme 2: Synthesis of (R)-4 and Velcade.
Figure 1: ORTEP diagram of (S,S,R)-3a (left, most of the hydrogen atoms were omitted except the one on the ch...
Scheme 3: Synthesis of phosphinylimines and their borylation products.